Heterogeneous photochemical reaction enabled by an ultrasonic microreactor

نویسندگان

چکیده

A novel ultrasonic microreactor is demonstrated for the heterogeneous silyl radical-mediated metallaphotoredox cross-electrophile coupling.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Microreactor-controlled selectivity in organic photochemical reactions*

Molecular-sieve zeolites, Nafion membranes, low-density polyethylene films, and mixed surfactant vesicles have been used as microreactors to carry out organic photochemical reactions. The photo-cycloadditions of diaryl compounds with long flexible chains included in NaY zeolite or low-density polyethylene films yield intramolecular photocyclomers to the exclusion of intermolecular products. The...

متن کامل

Decomposition of Oxalate Precipitates by Photochemical Reaction

A photo-radiation method was applied to decompose oxalate precipitates so that it can be dissolved into dilute nitric acid. This work has been studied as a part of partitioning of minor actinides. Minor actinides can be recovered from high-level wastes as oxalate precipitates, but they tend to be coprecipitated together with lanthanide oxalates. This requires another partitioning step for mutua...

متن کامل

The Photochemical Reaction in Photosynthesis

Measurements of photosynthesis were made in continuous and flashing light of high intensity, using cells varying in chlorophyll content. The amount of chlorophyll present per molecule of carbon dioxide reduced per single flash of light was found to be about 2480 molecules. The length of time required for one unit in the photosynthetic mechanism to complete the cycle of photochemical and Blackma...

متن کامل

Partial depolymerization of pectin by a photochemical reaction.

Complex heterogeneous polysaccharides that comprise pectin were partially depolymerized by a photochemical reaction using ultraviolet light in the presence of titanium dioxide catalyst. In a period of 6h at pH 7, this UV/TiO(2) process decreased the average molecular weight of pectin from 400kDa to 200kDa. The characterization of the partially depolymerized pectin, which was fractionated by siz...

متن کامل

Heterogeneous catalysis inside a microreactor containing acid-functionalized polymer brushes

Microreactor technology represents a new and promising approach to carry out analytical and organic chemistry. 1 This is mainly due to the numerous advantages, especially in terms of increased surfaceto-volume ratio as a result of the downsizing of the dimensions (order of microns). This allows a better and faster mixing between the components of a reaction. The small dimensions created within ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Reaction Chemistry and Engineering

سال: 2023

ISSN: ['2058-9883']

DOI: https://doi.org/10.1039/d3re00154g